Hi Jitesh,
Your script is writing to "Current Users" but the Pulseway agent runs as a local system account. When you test via Powershell ISE, you're running it under a specific user account. When executing via Pulseway, the agent is executing it (as Local System, not a user account), which means, if the script runs successfully, you'll likely see your keys put into the physical registry location for Current Users, which is in "Computer\HKEY_USERS\.DEFAULT\..."
Tim got a reaction from Jamie Taylor in HELP - Successfully runs the Enable SSO PowerShell script via Pulseway RMM, but does not execute on the endpoint